Treatment of phosphogypsum waste using suitable organic extractants

نویسندگان

  • H. El-Didamony
  • M. M. Ali
  • N. S. Awwad
  • M. M. Fawzy
  • M. F. Attallah
چکیده

Phosphogypsum (PG) is a residue of the phosphate fertilizer industry that has relatively high concentrations of harmful radioactive materials. The reduction in concentration of the radionuclides from PG was investigated. The removal process is based on leaching of radionuclides using suitable organic extractants. The studied radionuclides were 226Ra, 210Pb, 238U and 40K. The factors affect the leaching process such as type of leaching materials, contact time, concentration of the desired solvent, liquid to solid ratio, and temperature were studied. Based on the experimental results, about 71.1, 76.4, 62.4, and 75.7% of 226Ra, 210Pb, 238U and 40K respectively were successfully removed from the PG. The reduction in the concentration of radionuclides was accompanied by reduction in the concentration of rare earth elements (∑REE) equals to 69.8%. Using the desired organic extractant under optimum conditions for treatment of the PG waste leads to obtain a decontaminated product that can be safely used in many industrial applications.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Palladium-catalyzed cross-coupling of various phosphorus pronucleophiles with chloropyrazines: synthesis of novel Am(III)-selective extractants.

Palladium-catalyzed cross-coupling of (di)chloropyrazines with phosphorus pronucleophiles in the presence of a base gave the phosphorylated pyrazines in 81-95% yields. Based on this methodology a series of appropriately functionalized pyrazines was prepared as potential extractants of trivalent cations from highly acidic nuclear waste. A few hydrophilic derivatives exhibited a very good selecti...

متن کامل

First insight into microbial community composition in a phosphogypsum waste heap soil.

The aim of this study was to investigate the soil microbial communities of a phosphogypsum waste heap. The soil microbial community structures can differ over time, as they are affected by the changing environmental conditions caused by a long-term exposure to different kinds of pollutions, like is the case of soil in the post-production waste area in Wiślinka (in the northern part of Poland) c...

متن کامل

Soil Washing to Remove Mixed Wastes

Objective The goal of this laboratory exercise is to acquaint students with some of the chemical reactions that result in the binding of inorganic and organic pollutants in subsurface materials. Extractants used by engineers to release contaminants at hazardous waste sites (where mixtures of both types of contaminants are present) may or may not prove effective, depending upon their mechanism o...

متن کامل

Extraction of Metals from Contaminated Materials , Sediments and Industrial Solid Waste Using a Novel Technology ( Servo Process

Selective Extraction and Recovery using Volatile Organic compounds is an emerging technology developed during the 1970s. This process can achieve the extraction of heavy metal contaminants from a matrix using a volatile organic reagent which passes through the feed material and reacts selectively with the desired metal salt, producing a volatile metal complex, removed from the matrix by a carri...

متن کامل

Additives aided composting of green waste: effects on organic matter degradation, compost maturity, and quality of the finished compost.

The effect of various additives such as fly ash, phosphogypsum, jaggery, lime, and polyethylene glycol on green waste composting was investigated through assessing their influence on microbial growth, enzymatic activities, organic matter degradation, bulk density, quality of finished compost including gradation test, heavy metal analysis, etc. A perusal of results showed that addition of jagger...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 291  شماره 

صفحات  -

تاریخ انتشار 2012